When calcium phosphate is formed in boiler water of sufficient alkalinity (pH 11.0-12.0), a particle with a relatively nonadherent surface charge is produced. This does not prevent the development of deposit accumulations over time, but the deposits can be controlled reasonably well by blowdown.
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In this method, no free caustic is maintained in the boiler water. Figure 11.14 shows resulting pH versus phosphate concentration, the resulting pH on addition of trisodium phosphate. Trisodium phosphate hydrolyzes to produce hydroxide ions. Phosphate acts as buffer to minimize caustic cracking.
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29/4/2020 · Proper boiler water treatment eliminates sludge and scale deposits within the boiler. However, over along period of time a film of copper and iron oxides build up on the tube surface. Most of these oxides are transported from oxides of corrosion within the feed system to the boiler …
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Boiler water is liquid water within a boiler, or in associated piping, pumps and other equipment, that is intended for evaporation into steam.The term may also be applied to raw water intended for use in boilers, treated boiler feedwater, steam condensate being returned to a boiler, or boiler blowdown being removed from a boiler.
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Boiler Water Phosphate Chemistry 00 Purpose The purpose of this bulletin is to re-emphasize to all utility operators the potential chemistry control prob- lems that can lead to serious furnace tube corrosion. Monitoring of boiler water chemicals has always been
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17/10/2016 · -Prepare a solution of tri-sodium phosphate and di-sodium phosphate as per dosage mentioned in DM water and charge the chemicals in to the boiler drum through the manhole by several increments. The entire quantity of the chemicals is dosed in to the boiler.
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Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate.
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• New boiler water treatment was developed using the alkalinity derived from phosphate alone, eliminating sodium hydroxide – The sodium to phosphate ratio determines the pH of the water (3:1) – Ratio of trisodium to monosodium or disodium phosphate is
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The Function of Tri sodium Phosphate dosing in Boiler water is to condition feed water to ensure that plant involved in the steam / water cycle is kept free from corrosion. Tri – sodium phosphate solution is to be dosed in Boiler Drum / HRSG Drums to maintain water PH, to minimize potential acid and caustic corrosion in the drums.
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Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate, by the following reaction: Na 2 HPO 4 Get A
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30/4/2011 · Boiler water quality is of prime concern to all boiler operators. The process of water treatment in boilers is not limited to producing high quality DM water. The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation. This necessitates the use of a high quality water treatment system.
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• New boiler water treatment was developed using the alkalinity derived from phosphate alone, eliminating sodium hydroxide – The sodium to phosphate ratio determines the pH of the water (3:1) – Ratio of trisodium to monosodium or disodium phosphate is
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Description of water treatment in boilers: internal and external treatment The treatment and conditioning of boiler feed water must satisfy three main objectives: Continuous heat exchange Corrosion protection Production of high quality steam External treatment is the reduction or removal of impurities from water outside the boiler.
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• Brining Reactions: CaCl + Boiler Water CaSO 4 + CaSiO 3 • Phosphate Reactions: Ca 3 (PO 4) 2 Tricalcium Phosphate [Low Alk.] • Phosphate Reaction: Ca 10 (OH) 2 (PO 4) 6 Hydroxyapatite [Adequate Alkalinity] • Magnesium Reactions: Mg 3 (PO 4)
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